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{Synthesis, structure, and reactivity of [RuCl(PP)L]PF6 (PP = (PPh3)(2), Ph2P(CH2)(4)PPh2; L = P(py)(3), PPh(py)(2)

Title{Synthesis, structure, and reactivity of [RuCl(PP)L]PF6 (PP = (PPh3)(2), Ph2P(CH2)(4)PPh2; L = P(py)(3), PPh(py)(2)
Publication TypeJournal Article
Year of Publication1997
AuthorsSchutte, RP, Rettig, SJ, Joshi, AM, James, BR
JournalInorganic Chemistry
Volume36
Pagination5809-5817
Date PublishedDec
Type of ArticleArticle
ISBN Number0020-1669
Keywords2-(DIPHENYLPHOSPHINO)PYRIDINE, BRIDGING LIGAND, COORDINATION, HYDROFORMYLATION, palladium complexes, PHOSPHINE COMPLEXES, rhodium, RUTHENIUM(II) COMPLEXES
Abstract

{The complexes [RuCl(PPh3)(2)(P, N, N’-PPh3-x(py)(x))]PF6 (x = 2, 1b; 3, 1c; py = 2-pyridyl) were isolated from the reaction of RuCl2(PPh3)(3) with 1 equiv of PPh3-x(py)(x) and NH4PF6 in acetone. Crystals of 1b (C52H43ClF6N2P4Ru) are monoclinic

URL<Go to ISI>://A1997YK96400025