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Synthesis, characterization, and reactivity of a ruthenium(II) N,N’,N’’-tris(2-pyridyl)phosphine complex. X-ray analysis of RuCl2(PPh(3))(Ppy(3)) (py equals 2-pyridyl)

TitleSynthesis, characterization, and reactivity of a ruthenium(II) N,N’,N’’-tris(2-pyridyl)phosphine complex. X-ray analysis of RuCl2(PPh(3))(Ppy(3)) (py equals 2-pyridyl)
Publication TypeJournal Article
Year of Publication1996
AuthorsSchutte, RP, Rettig, SJ, James, BR
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume74
Pagination2064-2072
Date PublishedNov
Type of ArticleArticle
ISBN Number0008-4042
KeywordsCOORDINATION, crystal structure, CRYSTAL-STRUCTURE, LIGANDS, MOLECULAR-STRUCTURES, phosphine, pyridylphosphines, ruthenium
Abstract

{Reaction of RuCl2(PPh(3))(3) with Ppy(3) (py = 2-pyridyl) in benzene produced the N,N’,N ’’-Ppy(3) complex RuCl2(PPh(3))(Ppy(3)) 1. Crystals of RuCl2(PPh(3))(Ppy(3)). 2CH(2)Cl(2)(C35H31Cl6N3P2Ru) are monoclinic

URL<Go to ISI>://A1996WC12400022