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ROUTES TO RUTHENIUM(II) BROMO(SULFOXIDE) COMPLEXES, INCLUDING THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEUTRAL DILITHIUM DIRUTHENIUM(II) COMPLEX CONTAINING TERMINAL AND BRIDGING TETRAMETHYLENE SULFOXIDE LIGANDS

TitleROUTES TO RUTHENIUM(II) BROMO(SULFOXIDE) COMPLEXES, INCLUDING THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NEUTRAL DILITHIUM DIRUTHENIUM(II) COMPLEX CONTAINING TERMINAL AND BRIDGING TETRAMETHYLENE SULFOXIDE LIGANDS
Publication TypeJournal Article
Year of Publication1993
AuthorsJaswal, JS, Yapp, DTT, Rettig, SJ, James, BR, Skov, KA
JournalInorganica Chimica Acta
Volume207
Pagination97-103
Date PublishedMay
Type of ArticleArticle
ISBN Number0020-1693
KeywordsCHELATION, CRYSTAL-STRUCTURE, DIMETHYLSULFOXIDE, OXIDATION, SOLUTION CHEMISTRY, SULFOXIDE)RUTHENIUM(II), SULFOXIDE)TETRACHLORORUTHENATE(III), VERSATILE STARTING MATERIALS
Abstract

{The dimeric Ru(II) complex [Br6(TMSO)2Ru2(mu2-TMSO)2(mu3-TMSO)2Li2(TMSO)2] (1) has been isolated from solutions containing RuCl3.3H3O, LiBr and TMSO (TMSO = tetramethylene sulfoxide, O and S indicating oxygen- and sulfur-bonding, respectively). Crystals of 1 are monoclinic

URL<Go to ISI>://A1993LB77600014