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A DIRUTHENIUM DILITHIUM COMPLEX CONTAINING 4 DIFFERENT BONDING TYPES OF TETRAMETHYLENESULFOXIDE LIGANDS

TitleA DIRUTHENIUM DILITHIUM COMPLEX CONTAINING 4 DIFFERENT BONDING TYPES OF TETRAMETHYLENESULFOXIDE LIGANDS
Publication TypeJournal Article
Year of Publication1992
AuthorsJaswal, JS, Yapp, DTT, Rettig, SJ, James, BR, Skov, KA
JournalJournal of the Chemical Society-Chemical Communications
Pagination1528-1529
Date PublishedOct
Type of ArticleArticle
ISBN Number0022-4936
KeywordsCRYSTAL-STRUCTURE, RUTHENIUM(III) COMPLEXES, SOLUTION CHEMISTRY, SULFOXIDE COMPLEXES, SULFOXIDE)RUTHENIUM(II), SULFOXIDE)TETRACHLORORUTHENATE(III)
Abstract

The tetranuclear complex [Br6(tmso)2Ru2(mu2-tmso)2(mu3-tmso)2Li2(tmso)2] (tmso = tetramethylenesulfoxide; s and o imply sulfur- and oxygen-bonded sulfoxide, respectively) has been synthesized; four types of coordinated tmso are present, including a unique mu3-type.

URL<Go to ISI>://A1992JV20200029