| Title | Bisphosphine ligands containing two o-N,N-dimethylanilinyl substituents at each phosphorus atom |
| Publication Type | Journal Article |
| Year of Publication | 2002 |
| Authors | Jones, ND, Meessen, P, Smith, MB, Losehand, U, Rettig, SJ, Patrick, BO, James, BR |
| Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
| Volume | 80 |
| Pagination | 1600-1606 |
| Date Published | Nov |
| Type of Article | Article |
| ISBN Number | 0008-4042 |
| Keywords | ACID, amine, AMPHIPHILIC DIPHOSPHINES, CATALYTIC-HYDROGENATION, CHEMISTRY, DERIVATIVES, HYDROFORMYLATION, hydrogen-bonding to N atoms, phosphine, polydentate, RESOLUTION, RHODIUM COMPLEXES, RUTHENIUM(II), WATER-SOLUBLE PHOSPHINES |
| Abstract | The synthesis and complete characterization of the family of tetra(amine)bisphosphine ligands (o-NMe2C6H4)(2)P-(X)-P(o-NMe2C6H4)(2), where X = CH2 (dmapm), (CH2)(2) (dmape), and CH(CH2)(3)CH (dmapcp), are described. Crystal structure data are compared with known, analogous bisphosphines containing o-pyridyl or phenyl substituents in place of the o-dimethylanilinyl groups. Several short, intramolecular C-H...N distances in the anilinyl derivatives may represent the presence of weak hydrogen bonds. |
| URL | <Go to ISI>://000179703800030 |
