Title | Bis(ligand) rhenium(V) and technetium(V) complexes of two naturally occurring binding moieties (oxazoline and thiazoline) |
Publication Type | Journal Article |
Year of Publication | 1996 |
Authors | Shuter, E, Hoveyda, HR, Karunaratne, V, Rettig, SJ, Orvig, C |
Journal | Inorganic Chemistry |
Volume | 35 |
Pagination | 368-372 |
Date Published | Jan |
Type of Article | Article |
ISBN Number | 0020-1669 |
Keywords | COORDINATION CHEMISTRY, RADIOPHARMACEUTICALS, RAY CRYSTAL-STRUCTURE, SIDEROPHORE, TC-99M |
Abstract | {Attempts to prepare tris(ligand) metal complexes of technetium in intermediate oxidation states with potentially bidentate oxazoline- and thiazoline-containing ligands were unsuccessful; when pertechnetate was reduced in the presence of excess ligand, TcO2 . xH(2)O was produced. Instead, by reaction with preformed M . O cores, a series of oxotechnetium(V) and oxorhenium(V) complexes of the formula MOXL(2) (M = Re |
URL | <Go to ISI>://A1996TR24000018 |
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