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Synthesis, Structure, and Magnetic Properties of Bithiophene- and Terthiophene-Linked Manganese Metal Organic Frameworks

TitleSynthesis, Structure, and Magnetic Properties of Bithiophene- and Terthiophene-Linked Manganese Metal Organic Frameworks
Publication TypeJournal Article
Year of Publication2013
AuthorsEarl, LD, Patrick, BO, Wolf, MO
JournalINORGANIC CHEMISTRY
Volume52
Pagination10021-10030
Date PublishedSEP 2
ISSN0020-1669
Abstract

{A series of metal-organic frameworks (MOFs) containing manganese centers and oligothiophene dicarboxylate linkers have been synthesized: {[}Mn(3PhT(2)DC)(DMF)(0.4)s(F12.0)2..s5.1.5 5DMF] (1), {[}Mn6(3F1T2PC)6. (DMF)3(-120)5{''}xDMF{''}YH20] (2), {[}Mn(T3DC)(H20)2] (3), {[}Mn(T3DC)(H20)1.3] (4), and {[}Mn(Ph2T3DC)(DMF)2] (5) (H23PhT2DC = 3,3'-dipheny1-2,2-bithiophene-5,5'-dicarboxylic acid; H23HT2DC:= 3,3'-dihexy1-2,2'bithiophene-5,5'-dicarboxylic acid; H2T3DC = 2,2':5',2{''}{''}.ter,thiophene-5,5 `-dicarboxylic acid; H2Ph2T3DC = 3',4'-dipheny1-2,2':5',2{''}-terthiophene-5,5{''}-dicarboxylic acid

DOI10.1021/ic40130sc