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Synthesis, structure, and luminescent properties of oligothiophene-containing metal-organic frameworks

TitleSynthesis, structure, and luminescent properties of oligothiophene-containing metal-organic frameworks
Publication TypeJournal Article
Year of Publication2012
AuthorsEarl, LD, Patrick, BO, Wolf, MO
JournalCRYSTENGCOMM
Volume14
Pagination5801-5808
ISSN1466-8033
Abstract

{Metal-organic frameworks (MOFs) based on Zn and functionalized bithiophene dicarboxylic acids are reported, {[}Zn-2(L1)(2)(DMA)(2)center dot 3 DMF](n) (1), {[}Zn(L2)(DMA)(2)](n) (2), {[}Zn(L3)(bpe)(0.5)](n) (3), {[}Zn(L1)(bpe)center dot 2 DMF](n) (4), and {[}Zn-3(L2)(3)(bpe)(2)center dot 4 DMF center dot H2O](n)(5) (H(2)L1 = 3,3'-diphenyl-2,2'-bithiophene-5,5'-dicarboxylic acid, H(2)L2 = 3,3'-dihexyl-2,2'-bithiophene-5,5'-dicarboxylic acid, H(2)L3 = 2,2'-bithiophene-5,5'-dicarboxylic acid

DOI10.1039/c2ce25529d