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SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TRANS-RU(X)(CL)(NBD)(DPPB) (X = H, CL - NBD = 2,5-NORBORNADIENE - DPPB = 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE), INCLUDING THE X-RAY CRYSTAL-STRUCTURE OF THE DICHLORIDE

TitleSYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF TRANS-RU(X)(CL)(NBD)(DPPB) (X = H, CL - NBD = 2,5-NORBORNADIENE - DPPB = 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE), INCLUDING THE X-RAY CRYSTAL-STRUCTURE OF THE DICHLORIDE
Publication TypeJournal Article
Year of Publication1990
AuthorsDekleva, TW, Joshi, AM, Thorburn, IS, James, BR, Evans, SV, Trotter, J
JournalIsrael Journal of Chemistry
Volume30
Pagination343-350
Type of ArticleArticle
ISBN Number0021-2148
KeywordsASYMMETRIC HYDROGENATION, CARBON-MONOXIDE, CATALYSIS, COMPLEXES, DIHYDROGEN, DIOXYGEN, rhodium
Abstract

{The ruthenium (II) diene complexes [Ru(X)(Cl)(nbd)(dppb)] (X = Cl, H; nbd = 2,5-norbornadiene; dppb = PPh2(CH2)4PPh2) have been prepared and characterized spectroscopically. The X-ray crystal structure of RuCl2(nbd)(dppb) (crystal data at 22-degrees-C: space group PlBAR

URL<Go to ISI>://A1990FD55600007