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Synthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I)

TitleSynthesis and X-ray structures of water-soluble tris(hydroxymethyl)phosphine complexes of rhodium(I)
Publication TypeJournal Article
Year of Publication2007
AuthorsLorenzini, F, Patrick, BO, James, BR
JournalDalton Transactions
Pagination3224-3226
Date PublishedAug
ISBN Number1477-9226
Abstract

The water-soluble Rh-1-THP complexes: RhCl(1,5-cod)(THP) (1), [Rh(1,5-cod)(THP)(2)]Cl (2), RhCl(THP)4 (3), and trans-RhCl(CO)(THP)(2) (4) have been synthesized and characterized, where THP = P(CH2OH)(3); 1-3 are the first potentially useful entries into Rh-1-THP chemistry, while 1 and 4 are the first structurally characterized Rh-1-THP complexes.

URL<Go to ISI>://000249096400003