| Title | Synthesis and molecular structure of 4-methoxyphenyl-2 ’-pyrrolylthione and its rhenium complex |
| Publication Type | Journal Article |
| Year of Publication | 2003 |
| Authors | Selivanova, SV, Dolphin, D, van Lier, JE, Kudrevich, SV |
| Journal | Inorganica Chimica Acta |
| Volume | 349 |
| Pagination | 58-64 |
| Date Published | Jun |
| Type of Article | Article |
| ISBN Number | 0020-1693 |
| Keywords | 4-methoxyphenyl-2 ’-pyrrolylthione, CRYSTAL-STRUCTURE, LIGAND, N, S-ligand, X-ray diffraction study |
| Abstract | {A bidentate monoanionic N,S-ligand, 4-methoxyphenyl-2’-pyrrolylthione (1) was synthesised via an oxygen-to-sulphur exchange in the corresponding ketone and then fully characterised. A trinuclear complex (2) of rhenium with this compound was obtained in a reaction of KReO4 with 1 in the presence of a reducing agent in aqueous ethanol, followed by slow precipitation from chloroform-hexane. The structure of compound 2 corresponds to the formula [Re3O4(C12H10NOS)(6)](+1)[ReO4](-1).2CH(3)CH(2)OH. A single crystal X-ray diffraction study was performed for this complex. The following crystal data were obtained for 2: M-r = 2262.556, monoclinic, space group C2/c |
| URL | <Go to ISI>://000183673100008 |
