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Synthesis and characterization of the mixed valence Cu(I)/Cu(II) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]

TitleSynthesis and characterization of the mixed valence Cu(I)/Cu(II) 3,5-bis(trifluoromethyl)-pyrazolate complex, [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]
Publication TypeJournal Article
Year of Publication1997
AuthorsEhlert, MK, Storr, A, Summers, DA, Thompson, RC
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume75
Pagination491-498
Date PublishedMay
Type of ArticleArticle
ISBN Number0008-4042
Keywords3, 5-bis(trifluoromethyl)pyrazolates, ANTIFERROMAGNETISM, copper, COPPER(II) COMPLEX, MAGNETIC-PROPERTIES, METAL PYRAZOLATE POLYMERS, RAY CRYSTAL-STRUCTURE, STRUCTURE, trimetallic, X-RAY
Abstract

{The reaction of molten 3,5-bis(trifluoromethyl)pyrazole (F(6)dmpzH) with copper metal shot under an atmosphere of dioxygen yields the green trimetallic mixed valence [Cu(II)(2)Cu(I)(F(6)dmpz)(5)]. Crystals of [Cu(II)(2)Cu(I)F(6)dmpz)(5)] are triclinic

URL<Go to ISI>://A1997XF49200003