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  3. SYNTHESIS AND CHARACTERIZATION OF DIHALOGENORUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, DIPHENYLRUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, AND PHENYLRUTHENIUM(III)-TETRAPHENYLPORPHYRIN COMPLEXES, INCLUDING THE CRYSTAL-STRUCTURE OF RU(TPP)BR2

SYNTHESIS AND CHARACTERIZATION OF DIHALOGENORUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, DIPHENYLRUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, AND PHENYLRUTHENIUM(III)-TETRAPHENYLPORPHYRIN COMPLEXES, INCLUDING THE CRYSTAL-STRUCTURE OF RU(TPP)BR2

TitleSYNTHESIS AND CHARACTERIZATION OF DIHALOGENORUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, DIPHENYLRUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, AND PHENYLRUTHENIUM(III)-TETRAPHENYLPORPHYRIN COMPLEXES, INCLUDING THE CRYSTAL-STRUCTURE OF RU(TPP)BR2
Publication TypeJournal Article
Year of Publication1991
AuthorsKe, M, Sishta, C, James, BR, Dolphin, D, Sparapany, JW, Ibers, JA
JournalInorganic Chemistry
Volume30
Pagination4766-4771
Date PublishedDec
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCARBONYL-COMPLEXES, DIOXYGEN INSERTION, IRON(II) PORPHYRINS, MOLECULAR-STRUCTURES, NUCLEAR MAGNETIC-RESONANCE, OXO COMPLEXES, PORPHYRIN COMPLEXES, redox properties, RUTHENIUM PORPHYRIN, Schiff-base
Abstract

{The paramagnetic (S = 1) Ru(TPP)X2 complexes (X = halide) are made by treatment of [Ru(TPP)]2 with HBr, HCl, or I2 (TPP = the dianion of 5,10,15,20-tetraphenylporphyrin). The dibromo species (2) crystallizes in the tetragonal system, space group C4h5-I4/m, with a = 13.686 (9) angstrom
URL<Go to ISI>://A1991GT93800017