Research & Teaching Faculty

  1. Research & Teaching Faculty
  2. Department Publications
  3. STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .56. 1-BENZYL-7-METHYL-3,5-DIPHENYL-2,4,6-TRIOXA-1-AZONIA-3-BORA-5-BORATABICY CLO[3.3.0]OCTANE AND 1,4,6,9-TETRAMETHYL-2,7-DIPHENYL-3,8,11,12-TETRAOXA-1,6-DIAZONIA-2,7-DIB ORATATRICYCLO[5.3.1.1(2,6)]DODECANE

STRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .56. 1-BENZYL-7-METHYL-3,5-DIPHENYL-2,4,6-TRIOXA-1-AZONIA-3-BORA-5-BORATABICY CLO[3.3.0]OCTANE AND 1,4,6,9-TETRAMETHYL-2,7-DIPHENYL-3,8,11,12-TETRAOXA-1,6-DIAZONIA-2,7-DIB ORATATRICYCLO[5.3.1.1(2,6)]DODECANE

TitleSTRUCTURAL STUDIES OF ORGANOBORON COMPOUNDS .56. 1-BENZYL-7-METHYL-3,5-DIPHENYL-2,4,6-TRIOXA-1-AZONIA-3-BORA-5-BORATABICY CLO[3.3.0]OCTANE AND 1,4,6,9-TETRAMETHYL-2,7-DIPHENYL-3,8,11,12-TETRAOXA-1,6-DIAZONIA-2,7-DIB ORATATRICYCLO[5.3.1.1(2,6)]DODECANE
Publication TypeJournal Article
Year of Publication1992
AuthorsKliegel, W, Lubkowitz, G, Rettig, SJ, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination2809-2817
Date PublishedNov
Type of ArticleArticle
ISBN Number0008-4042
KeywordsC-H...O, CRYSTAL, MOLECULAR-STRUCTURE
Abstract

{The preparation of the N-(2-hydroxypropyl)-N-alkylhydroxylamines, 6a (R = CH3) and 6b (R = CH2Ph), and their reactions with phenylboronic acid are described. Regardless of the molar ratios of reactants employed, the reaction with 6b leads to the 1:2 condensate 1-benzyl-7-methyl-3,5-diphenyl-2,4,6-trioxa-1-azonia-3-bora-5-boratabicy clo[3.3.0]octane, 7, while that with 6a gives rise to the 1:1 condensate 1,4,6,9-tetramethyl-2,7-diphenyl-3,8,11,12-tetraoxa-1,6-diazonia-2,7-dib oratatricyclo[5.3.1.1(2,6)]dodecane, 11 (the cyclic BONBON dimer of 4,6-dimethyl-2-phenyl-1,3-dioxa-4-aza-2-boracyclohexane, 9). Compounds 7 and 11 both crystallize in the triclinic space group P1BAR: for 7; a = 13.126(1)
URL<Go to ISI>://A1992KC74200017