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Stoichiometric O-2 oxidation of bis(thioether) (octaethylporphyrinato)ruthenium(II) complexes to the corresponding sulfoxide species in acidic media. Structural confirmation of S-bonded sulfoxides

TitleStoichiometric O-2 oxidation of bis(thioether) (octaethylporphyrinato)ruthenium(II) complexes to the corresponding sulfoxide species in acidic media. Structural confirmation of S-bonded sulfoxides
Publication TypeJournal Article
Year of Publication1999
AuthorsPacheco, A, James, BR, Rettig, SJ
JournalInorganic Chemistry
Volume38
Pagination5579-5587
Date PublishedNov
Type of ArticleArticle
ISBN Number0020-1669
KeywordsACETONITRILE SOLUTION, CRYSTAL, ELECTRON-TRANSFER, LIGANDS, MOLECULAR-STRUCTURE, porphyrins, RUTHENIUM(II)
Abstract

{Exposure to o(2) (or air) of a CH2Cl2, benzene, or toluene solution containing PhCO2H and Ru(OEP)(RR’S)(2) (where OEP = the dianion of 2,3,7,8,12,13,17,1 8-octaethylporphyrin

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