Title | The solid-state molecular structure of W(NO)(3)Cl-3 and the nature of its W-NO bonding |
Publication Type | Journal Article |
Year of Publication | 2004 |
Authors | Hayton, TW, Patrick, BO, Legzdins, P, McNeil, WS |
Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
Volume | 82 |
Pagination | 285-292 |
Date Published | Feb |
Type of Article | Article |
ISBN Number | 0008-4042 |
Keywords | bonding, CARBONYL, CHEMISTRY, CRYSTAL-STRUCTURE, DERIVATIVES, DICHLORODINITROSYLTUNGSTEN, DICHLOROTRINITROSYLVANADIUM, MOLYBDENUM, MONONUCLEAR, NITROSYL, NITROSYL COMPLEXES, STRUCTURE, TUNGSTEN |
Abstract | {The monomeric trinitrosyl complex, W(NO)(3)Cl-3, can be prepared by the treatment of WCl6 in CH2Cl2 with NO gas, and its identity has been unambiguously confirmed by a single-crystal X-ray diffraction analysis. The complex crystallizes in the space group Pmn2(1) as a three-component twin (a = 10.4280(4) Angstrom |
URL | <Go to ISI>://000220138500024 |
