| Title | The safe and convenient preparation of bis(fluorosulfuryl) peroxide (S2O6F2) on a large scale |
| Publication Type | Journal Article |
| Year of Publication | 1996 |
| Authors | Zhang, D, Wang, C, Mistry, F, Powell, B, Aubke, F |
| Journal | Journal of Fluorine Chemistry |
| Volume | 76 |
| Pagination | 83-89 |
| Date Published | Jan |
| Type of Article | Article |
| ISBN Number | 0022-1139 |
| Keywords | AgF2 catalysis, bis(fluorosulfuryl), catalytic fluorination, DERIVATIVES, flow reactor design, FLUOROSULFATE, FOSO2F, peroxide synthesis |
| Abstract | The design and construction of a catalytic reactor (AgF2 on copper turnings as support) for the fluorination of SO3 in a flow reaction to produce bis(fluorosulfuryl) peroxide (S2O6F2) are described in detail. An operating procedure is developed that allows the production of S2O6F2 in substantial quantities (80-120 g h(-1)) and avoids the accidental production of fluorine fluorosulfate (FOSO2F) as a hazardous byproduct. Also described are purification methods and disposal procedures for highly reactive byproducts (F-2 or FOSO2F) in a safe and environmentally friendly manner, as well as the long-term storage of S2O6F2. |
| URL | <Go to ISI>://A1996TW37300016 |
