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Rhodium(I)-(N-heterocyclic carbene)-diphosphine complexes

TitleRhodium(I)-(N-heterocyclic carbene)-diphosphine complexes
Publication TypeJournal Article
Year of Publication2009
AuthorsSun, HS, Yu, XY, Marcazzan, P, Patrick, BO, James, BR
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume87
Pagination1248-1254
Date PublishedSep
Type of ArticleArticle
ISBN Number0008-4042
KeywordsC-H ACTIVATION, CATALYTIC-ACTIVITY, HETEROCYCLIC CARBENE COMPLEXES, HYDROFORMYLATION, HYDROGENATION REACTIONS, HYDROSILYLATION, iridium complexes, LIGANDS, phosphine, RHODIUM(I) COMPLEXES
Abstract

{Les reactions du [RhCl(COE)(IPr)](2) (1) et du [RhCl(COE)(IMes)](2) (2) [COE = cyclooctene; IPr = N,N’-bis(2,6-diisopropylphenyl)imidazoline-2-ylidene; IMes = N,N’-bis(2,4,6-trimethylphenyl)imidazoline-2-ylidene] avec les diphosphines Ph2P(CH2)(n)PPh2 et 1,2-bis(diphenylphosphino)benzene (dppbz) conduisent a la formation de complexes carbene N-heterocyclique (NHC) - diphosphine - rhodium(I): RhCl(NHC)[Ph2P(CH2)(n)PPh2] [NHC = IPr

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