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Reversible molecular switching of ruthenium bis(bipyridyl) groups bonded to oligothiophenes: Effect on electrochemical and spectroscopic properties

TitleReversible molecular switching of ruthenium bis(bipyridyl) groups bonded to oligothiophenes: Effect on electrochemical and spectroscopic properties
Publication TypeJournal Article
Year of Publication2005
AuthorsMoorlag, C, Wolf, MO, Bohne, C, Patrick, BO
JournalJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume127
Pagination6382-6393
Date PublishedMAY 4
ISSN0002-7863
Abstract

{We report the preparation of complexes in which ruthenium(II) bis(bipyridyl) groups are coordinated to oligothiophenes via a diphenylphosphine linker and a thienyl sulfur (P,S bonding) to give {[}Ru(bpy)(2)PT3P,S](PF6)(2) (bpy = 2,2'-bipyridyl

DOI10.1021/ja043573a