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A remarkable temperature-dependent, accidental degeneracy of P-31 NMR chemical shifts in Ru(II) diphosphine/diimine complexes

TitleA remarkable temperature-dependent, accidental degeneracy of P-31 NMR chemical shifts in Ru(II) diphosphine/diimine complexes
Publication TypeJournal Article
Year of Publication2001
AuthorsCyr, PW, Patrick, BO, James, BR
JournalChemical Communications
Pagination1570-1571
Date PublishedSep
Type of ArticleArticle
ISBN Number1359-7345
KeywordsASYMMETRIC HYDROGENATION, BINAP, CATALYSIS, CHEMISTRY, DERIVATIVES, KETONES, LIGANDS, PHOSPHINE COMPLEXES, REACTIVITY, RUTHENIUM(II) COMPLEXES
Abstract

Several cis-RUX2((R)-BINAP)(diimine) complexes have been prepared, and many of these exhibit an unusual temperature-dependent, accidental degeneracy of the P-31 shifts in their solution NMR spectra.

URL<Go to ISI>://000170798800019