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Reactions of a Phosphinoaldehyde with Pd <sup>II</sup>, Rh <sup>I</sup>, and Ir <sup>I</sup> Precursors, Including the Formation of Complexes Containing a P,OH-Chelated Phosphinohemiacetal Ligand: a New Bonding Mode

TitleReactions of a Phosphinoaldehyde with Pd II, Rh I, and Ir I Precursors, Including the Formation of Complexes Containing a P,OH-Chelated Phosphinohemiacetal Ligand: a New Bonding Mode
Publication TypeJournal Article
Year of Publication2010
AuthorsLorenzini, F, Moiseev, D, Patrick, BO, James, BR
JournalInorganic Chemistry
Volume49
Pagination2111 - 2122
Date Published03/2010
ISSN1520-510X
Abstract

{The complexes trans-PdCl2[η1-P-(Ph2P)CH(Ph)CH(Me)CH(OMe)2]2 (1) and M(H)Cl[η2-P,OH-(Ph2P)CH(Ph)CH(Me)CH(OH)OMe][η2-P,C(O)-(Ph2P)CH(Ph)CH(Me)C(O)]

DOI10.1021/ic9015993