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  3. {POLYNUCLEAR PYRAZOLATE COMPLEXES OF COPPER - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(TMPZ)]3, [CU(3-CO2DMPZ)(TMPZH)]2CU, AND [CU(4-BR-3-CO2MEPZ)(4-BR-DMPZH)2]2 (WHERE MEPZ = METHYLPYRAZOLATE

{POLYNUCLEAR PYRAZOLATE COMPLEXES OF COPPER - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(TMPZ)]3, [CU(3-CO2DMPZ)(TMPZH)]2CU, AND [CU(4-BR-3-CO2MEPZ)(4-BR-DMPZH)2]2 (WHERE MEPZ = METHYLPYRAZOLATE

Title{POLYNUCLEAR PYRAZOLATE COMPLEXES OF COPPER - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(TMPZ)]3, [CU(3-CO2DMPZ)(TMPZH)]2CU, AND [CU(4-BR-3-CO2MEPZ)(4-BR-DMPZH)2]2 (WHERE MEPZ = METHYLPYRAZOLATE
Publication TypeJournal Article
Year of Publication1992
AuthorsEhlert, MK, Rettig, SJ, Storr, A, Thompson, RC, Trotter, J
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination2161-2173
Date PublishedAug
Type of ArticleArticle
ISBN Number0008-4042
KeywordsPOLYMERS
Abstract

{The reaction of molten trimethylpyrazole (tmpzH) with copper metal shot in air yields a mixture of the trinuclear copper(I) complex [Cu(tmpz)]3, 1, and the trinuclear copper(I/II) complex [Cu(3-CO2dmpz)(tmpzH)]2Cu, 2 (where dmpz is dimethylpyrazolate). Crystals of 1 are monoclinic
URL<Go to ISI>://A1992JW56400005