| Title | A pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes |
| Publication Type | Journal Article |
| Year of Publication | 2006 |
| Authors | Thomson, RK, Bexrud, JA, Schafer, LL |
| Journal | Organometallics |
| Volume | 25 |
| Pagination | 4069-4071 |
| Date Published | Aug |
| Type of Article | Article |
| ISBN Number | 0276-7333 |
| Keywords | ALKYNE HYDROAMINATION, allenes, AMIDATE COMPLEXES, BIS(AMIDATE) TITANIUM PRECATALYST, C-H ACTIVATION, HYDROAMINATION, INTERMOLECULAR HYDROAMINATION, INTRAMOLECULAR, REACTIVITY, TEMPERATURE, TI(NME2)(4) |
| Abstract | The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry. |
| URL | <Go to ISI>://000239536800007 |
