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A pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes

TitleA pentagonal pyramidal zirconium imido complex for catalytic hydroamination of unactivated alkenes
Publication TypeJournal Article
Year of Publication2006
AuthorsThomson, RK, Bexrud, JA, Schafer, LL
JournalOrganometallics
Volume25
Pagination4069-4071
Date PublishedAug
Type of ArticleArticle
ISBN Number0276-7333
KeywordsALKYNE HYDROAMINATION, allenes, AMIDATE COMPLEXES, BIS(AMIDATE) TITANIUM PRECATALYST, C-H ACTIVATION, HYDROAMINATION, INTERMOLECULAR HYDROAMINATION, INTRAMOLECULAR, REACTIVITY, TEMPERATURE, TI(NME2)(4)
Abstract

The first, isolable group 4 imido complexes capable of promoting intramolecular olefin hydroamination for the preparation of N-containing heterocycles are presented. The structurally characterized 6-coordinate bis(amidate)-supported zirconium imido complex is a rare example of distorted-pentagonal-pyramidal geometry.

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