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OXOBIS(2,4-PENTANEDIONATO)VANADIUM(IV), A REDETERMINATION

TitleOXOBIS(2,4-PENTANEDIONATO)VANADIUM(IV), A REDETERMINATION
Publication TypeJournal Article
Year of Publication1995
AuthorsShuter, E, Rettig, SJ, Orvig, C
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume51
Pagination12-14
Date PublishedJan
Type of ArticleArticle
ISBN Number0108-2701
KeywordsINSULIN
Abstract

A redetermination of oxobis(2,4-pentanedionato)vanadium(IV), [VO(C5H7O2)2], has been undertaken using high-resolution Mo data. Geometrical parameters do not differ significantly from those reported earlier [Dodge, Templeton and Zalkin (1961). J. Chem. Phys. 35, 55-67; Hen, Belford & Pfluger (1965). J. Chem. Phys. 43, 3111-3115], but the standard deviations are improved by an order of magnitude. Important structural parameters: V-O(basal) 1.967(1)-1.970(1)Angstrom and V=O(apical) 1.584(2)Angstrom.
URL<Go to ISI>://A1995QB32000006