| Title | Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel( I) delta-bis(C-H) Agostic Complex |
| Publication Type | Journal Article |
| Year of Publication | 2016 |
| Authors | D. Beattie, D, Bowes, EG, Drover, MW, Love, JA, Schafer, LL |
| Journal | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION |
| Volume | 55 |
| Pagination | 13290-13295 |
| Date Published | OCT 10 |
| ISSN | 1433-7851 |
| Abstract | Amidate-supported two-and three-coordinate Ni-I complexes were synthesized by reduction of the corresponding Ni-II precursors. A dramatic change in binding mode is observed upon reduction from Ni-II to Ni-I. The Ni-I derivatives include an unprecedented NiI bis(C-H) agostic complex and a two-coordinate Ni-I complex. |
| DOI | 10.1002/anie.201607243 |
