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  3. ORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE TETRAHEDRAL (TD) CUBANE [(ETA-C5(CH3)5)CR(MU-3-O)]4 AND COMPARISON WITH THE D2 [(ETA-C5H5)CR(MU-3-O)]4 AND D2D [(ETA-C5H4CH3)CR(MU-3-O)]4

ORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE TETRAHEDRAL (TD) CUBANE [(ETA-C5(CH3)5)CR(MU-3-O)]4 AND COMPARISON WITH THE D2 [(ETA-C5H5)CR(MU-3-O)]4 AND D2D [(ETA-C5H4CH3)CR(MU-3-O)]4

TitleORGANOMETALLIC OXIDES - PREPARATION AND PROPERTIES OF THE TETRAHEDRAL (TD) CUBANE [(ETA-C5(CH3)5)CR(MU-3-O)]4 AND COMPARISON WITH THE D2 [(ETA-C5H5)CR(MU-3-O)]4 AND D2D [(ETA-C5H4CH3)CR(MU-3-O)]4
Publication TypeJournal Article
Year of Publication1991
AuthorsBottomley, F, Chen, JH, Macintosh, SM, Thompson, RC
JournalOrganometallics
Volume10
Pagination906-912
Date PublishedApr
Type of ArticleArticle
ISBN Number0276-7333
Keywords(ETA-5-C5H5)4CR4O4, ANTI-FERROMAGNETIC COMPLEXES, CLUSTERS, METAL-METAL BONDS, MOLECULAR-STRUCTURES, TETRAHYDROFURAN
Abstract

{The cubane [(eta-C5(CH3)5)Cr(mu-3-O)]4 (3) was prepared by the reaction between (eta-C5(CH3)5)2Cr (4) and N2O (1:1 molar ratio) in toluene at 80-degrees-C. The structures of 3 and 4 have been determined by X-ray diffraction. 3: M(r) = 813.0, triclinic, P1BAR
URL<Go to ISI>://A1991FG97600021