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  3. The novel magnetic properties of SSSNCCNSSS(M)(2) (M=AsF6, Sb2F11) and the electronic properties of (SSSNCCNSSS+center dot)-S-center dot+

The novel magnetic properties of SSSNCCNSSS(M)(2) (M=AsF6, Sb2F11) and the electronic properties of (SSSNCCNSSS+center dot)-S-center dot+

TitleThe novel magnetic properties of SSSNCCNSSS(M)(2) (M=AsF6, Sb2F11) and the electronic properties of (SSSNCCNSSS+center dot)-S-center dot+
Publication TypeJournal Article
Year of Publication1996
AuthorsEnright, GD, Morton, JR, Passmore, J, Preston, KF, Thompson, RC, Wood, DJ
JournalChemical Communications
Pagination967-968
Date PublishedApr
Type of ArticleArticle
ISBN Number1359-7345
Abstract

The variable-temperature magnetic behaviour of the previously reported AsF6- and presently reported Sb2F11-salts of bis(1,2,3,4-trithiazolium), (SSSNCCNSSS+.)-S-.+ (1(2+)), are complex but indicate intermolecular antiferromagnetic interactions and temperature-independent paramagnetism, as well as intramolecular antiferromagnetic coupling leading to a singlet ground state, with a nearly degenerate thermally accessible triplet excited state, which is confirmed by EPR spectroscopy.
URL<Go to ISI>://A1996UJ31900038