|Title||The novel magnetic properties of SSSNCCNSSS(M)(2) (M=AsF6, Sb2F11) and the electronic properties of (SSSNCCNSSS+center dot)-S-center dot+|
|Publication Type||Journal Article|
|Year of Publication||1996|
|Authors||Enright, GD, Morton, JR, Passmore, J, Preston, KF, Thompson, RC, Wood, DJ|
|Type of Article||Article|
The variable-temperature magnetic behaviour of the previously reported AsF6- and presently reported Sb2F11-salts of bis(1,2,3,4-trithiazolium), (SSSNCCNSSS+.)-S-.+ (1(2+)), are complex but indicate intermolecular antiferromagnetic interactions and temperature-independent paramagnetism, as well as intramolecular antiferromagnetic coupling leading to a singlet ground state, with a nearly degenerate thermally accessible triplet excited state, which is confirmed by EPR spectroscopy.
|URL||<Go to ISI>://A1996UJ31900038|