| Title | FLUOROSULFATE DERIVATIVES OF DIVALENT GOLD |
| Publication Type | Journal Article |
| Year of Publication | 1991 |
| Authors | Willner, H, Mistry, F, Hwang, G, Herring, FG, Cader, MSR, Aubke, F |
| Journal | Journal of Fluorine Chemistry |
| Volume | 52 |
| Pagination | 13-27 |
| Date Published | Apr |
| Type of Article | Article |
| ISBN Number | 0022-1139 |
| Keywords | GOLD(III) FLUOROSULFATE, ION, palladium, SILVER(II), SPECTRA |
| Abstract | The reduction of gold(III) fluorosulfate, Au(SO3F)3 with either gold powder or carbon monoxide, in fluorosulfuric acid, HSO3F, yields gold(II) fluorosulfate as a yellow-red solid in high yield. Based on magnetic measurements and vibrational spectra, formulation as mixed valency Au(I) Au(III)-(SO3F)4 is suggested. Evidence from ESR measurements for a solvated, paramagnetic Au(II)-species in the supernatant solution is obtained and discussed. |
| URL | <Go to ISI>://A1991FL53900003 |
