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New Electrochemically Generated Polymeric Pd Complexes as Heterogeneous Catalysts for Suzuki Cross-Coupling Reactions

TitleNew Electrochemically Generated Polymeric Pd Complexes as Heterogeneous Catalysts for Suzuki Cross-Coupling Reactions
Publication TypeJournal Article
Year of Publication2009
AuthorsBandini, M, Pietrangelo, A, Sinisi, R, Umani-Ronchi, A, Wolf, MO
JournalEUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Pagination3554-3561
Date PublishedJUL
ISSN1434-193X
Abstract

Electrochemically generated films of polymerized (diamino-oligothiophene)palladium complexes as heterogeneous catalysts for Suzuki cross-coupling reactions are reported. The electrodeposition of these polymeric species onto porous graphite electrodes allows for easy removal of the organometallic species from the reaction mixture and convenient reuse in subsequent (up to 6) reactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

DOI10.1002/ejoc.200900306