Title | N-14 hyperfine structure in the pure rotational spectrum of (MgNC)-Mg-24-N-14-C-12 |
Publication Type | Journal Article |
Year of Publication | 1998 |
Authors | Walker, KA, Gerry, MCL |
Journal | Journal of Molecular Spectroscopy |
Volume | 189 |
Pagination | 40-45 |
Date Published | May |
Type of Article | Article |
ISBN Number | 0022-2852 |
Keywords | ABINITIO, INTERSTELLAR, IRC+10216, MG-BEARING MOLECULE, MILLIMETER, PARAMETERS, PREDICTION, RESONANCE, SEARCHES, spectroscopic constants |
Abstract | The pure rotational spectrum of (MgNC)-Mg-24-N-14-C-12, between 11.9 and 23.9 GHz, has been measured using a pulsed jet Fourier transform microwave spectrometer. The hyperfine structure due to the N-14 nucleus has been measured, and the nuclear quadrupole coupling, Fermi contact, and dipole-dipole interaction constants have been determined. The ionic character of the metal-isocyanide bond has been investigated through the nuclear quadrupole and magnetic hyperfine parameters. (C) 1998 Academic Press. |
URL | <Go to ISI>://000073499500005 |
