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MIXING SCHEMES AND LIQUID-SOLID PHASE-DIAGRAM IN THE WATER-RICH REGION OF AQUEOUS 2-BUTOXYETHANOL

TitleMIXING SCHEMES AND LIQUID-SOLID PHASE-DIAGRAM IN THE WATER-RICH REGION OF AQUEOUS 2-BUTOXYETHANOL
Publication TypeJournal Article
Year of Publication1994
AuthorsKoga, Y, Tanaka, T, Atake, T, Westh, P, Hvidt, A
JournalBulletin of the Chemical Society of Japan
Volume67
Pagination2393-2397
Date PublishedSep
Type of ArticleArticle
ISBN Number0009-2673
KeywordsBEHAVIOR, COEFFICIENTS, LIGHT-SCATTERING, MIXTURES, PARTIAL MOLAR ENTHALPIES, TEMPERATURES, TRANSITION, VOLUMES
Abstract

Liquid-solid phase diagram was determined in the water-rich region of aqueous 2-butoxyethanol. A solid addition compound was suggested with the composition x(BE)add = 0.0260, which melts incongruently at 269.5 K. The mixing scheme boundary separating two regions in the single liquid phase domain (Chem. Phys. Lett., 217, 245 (1994) was found to cross the incongruent melting point of the above solid addition compound.
URL<Go to ISI>://A1994PM79700008