| Title | Isomorphous substitution of silicon by boron or aluminum in layered silicates |
| Publication Type | Book Chapter |
| Year of Publication | 1995 |
| Authors | Schwieger, W, Pohl, K, Brenn, U, Fyfe, CA, Grondey, H, Fu, G, Kokotailo, GT |
| Editor | Beyer, HK, Karge, HG, Kiricsi, I, Nagy, JB |
| Book Title | Catalysis by Microporous Materials |
| Series Title | Studies in Surface Science and Catalysis |
| Volume | 94 |
| Pagination | 47-54 |
| Publisher | Elsevier Science Publ B V |
| City | Amsterdam |
| ISBN Number | 0-444-82049-3 |
| Keywords | MAGADIITE, NMR, SODIUM, STATE |
| Abstract | In order to systematically change the properties of layered silicate materials, we have investigated the possibility of isomorphous substitution of silicon by aluminum or boron. It is demonstrated that addition of boron and/or aluminum compounds to the reaction mixture leads directly to boron and aluminum containing layered materials in a hydrothermal crystallization process without further treatment. The layered materials obtained were identified as hectorite types, magadiite and kenyaite-like types. The isomorphous substitutions were pr-oven by B-11, Al-27, and Si-29 solid state MMR spectroscopy. |
| URL | <Go to ISI>://A1995BE31J00005 |
