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IRON OSMIUM BONDING IN CLUSTERS CONTAINING FERROCENE FRAGMENTS

TitleIRON OSMIUM BONDING IN CLUSTERS CONTAINING FERROCENE FRAGMENTS
Publication TypeJournal Article
Year of Publication1992
AuthorsCullen, WR, Rettig, SJ, Zheng, TC
JournalOrganometallics
Volume11
Pagination277-283
Date PublishedJan
Type of ArticleArticle
ISBN Number0276-7333
KeywordsATOM, COMPLEXES
Abstract

{Pyrolysis of Os3(CO)10(PFcPh2)2 and Os3(CO)11(PFc2Ph) affords Os3(CO)8(H)2[PAr(C6H5)(eta-C5H3)Fe(eta-C5H4)] (Ar = C6H5 (3a), Fc (3b), respectively). Os3(CO)7(H)(PPr(i))[Fe(eta-C5H4PPr(i)2)(eta-C5H4)] (4) is a product of the thermolysis of Os3(CO)10[Fe(eta-C5H4PPr(i)2)2]. 3b: triclinic, space group P1BAR (No. 2)

URL<Go to ISI>://A1992GZ04000050