|Title||The influence of chiral auxiliaries is enhanced within zeolites|
|Publication Type||Journal Article|
|Year of Publication||2000|
|Authors||Jayaraman, S, Uppili, S, Natarajan, A, Joy, A, Chong, KCW, Netherton, MR, Zenova, A, Scheffer, JR, Ramamurthy, V|
|Type of Article||Article|
|Keywords||ASYMMETRIC PHOTOCHEMICAL-REACTIONS, ESTERS, INDUCTION, MODEL, SOLID-STATE|
Zeolites significantly enhance the influence of chiral auxiliaries during photochemical reactions. The generality of this phenomenon has been tested with three independent examples. Chiral auxiliaries that lead to 1:1 mixtures of diastereomers in solution give products in up to 80% diastereomeric excess in the presence of faujasite type zeolites. (C) 2000 Elsevier Science Ltd. All rights reserved.
|URL||<Go to ISI>://000090123600010|