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Formation of ruthenium(II)-bis(phosphine) monoxide complexes from the bis(phosphine) precursors: BINAP-monoxide (BINAPO) as a six-electron (P,O,eta(2)-naphthyl) donor

TitleFormation of ruthenium(II)-bis(phosphine) monoxide complexes from the bis(phosphine) precursors: BINAP-monoxide (BINAPO) as a six-electron (P,O,eta(2)-naphthyl) donor
Publication TypeJournal Article
Year of Publication2002
AuthorsCyr, PW, Rettig, SJ, Patrick, BO, James, BR
JournalOrganometallics
Volume21
Pagination4672-4679
Date PublishedOct
Type of ArticleReview
ISBN Number0276-7333
KeywordsASYMMETRIC HYDROGENATION, CATALYTIC ENANTIOSELECTIVE, CHIRAL RUTHENIUM(II) CATALYSTS, COORDINATION CHEMISTRY, DIELS-ALDER REACTIONS, HYDROGENATION, MEO-BIPHEP, P-C BOND, PHOSPHINE OXIDE LIGANDS, STEREOSELECTIVE, X-RAY
Abstract

{Aerobic oxidation of one P atom in cis-RuCl2(P-P)(L-2) complexes (P-P = (R)-BINAP (2,2’-bis(diphenylphosphino)-1,1’-binaphthyl) or dppb (1,4-bis(diphenylphosphino)butane)

URL<Go to ISI>://000178778100015