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Fixation of amine copper preservatives Part 1. Reaction of vanillin, a lignin model compound with monoethanolamine copper sulphate solution

TitleFixation of amine copper preservatives Part 1. Reaction of vanillin, a lignin model compound with monoethanolamine copper sulphate solution
Publication TypeJournal Article
Year of Publication2001
AuthorsRuddick, JNR, Xie, CS, Herring, FG
JournalHolzforschung
Volume55
Pagination585-589
Type of ArticleArticle
ISBN Number0018-3830
Keywordscopper-ethanolamine, ESR, ethanolamine, FIXATION, LIGNIN MODEL COMPOUND, preservatives, VANILLIN, WOOD PRESERVATION, X-ray crystal structure
Abstract

{The fixation reaction of copper-ethanolamine preservatives in wood was studied using the reaction between vanillin, a lignin model compound, and ethanolamine-copper sulphate solution. The green compound precipitated after the reaction has been characterized spectroscopically as di(ethanolamine)bis (vanillinato)dicopper(II); [Cu(vanillin) (ethanolamine)],. Single crystal X-ray crystallographic studies showed that the crystals of [Cu(vanillin)(ethanolamine)](2) are triclinic with the space group P1 with a = 9.1271(7)

URL<Go to ISI>://000172786300005