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Facile Synthesis of Unsubstituted beta,beta ’-Linked Diformyldipyrromethanes

TitleFacile Synthesis of Unsubstituted beta,beta ’-Linked Diformyldipyrromethanes
Publication TypeJournal Article
Year of Publication2008
AuthorsZhang, Z, Shin, JY, Dolphin, D
JournalJournal of Organic Chemistry
Volume73
Pagination9515-9517
Date PublishedDec
Type of ArticleArticle
ISBN Number0022-3263
KeywordsACETALS, BUILDING-BLOCKS, CHEMISTRY, COMPLEXES, ISOMER, MESOSUBSTITUTED DIPYRROMETHANES, N-confused porphyrin, SALTS, SUBSTITUENTS, supramolecular, TETRAPYRROLE
Abstract

Unsubstituted beta,beta’-linked diformyldipyrromethanes are promising precursors for the synthesis of novel poly dipyrromethene ligands and N-confused porphyrins. A strategy has been developed to selectively synthesize unsubstituted beta,beta’-linked diformyldipyrromethanes in moderate yields starting from 2-formylpyrrole.
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