| Title | (eta(5)-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilyl- methyl)molybdenum(II) |
| Publication Type | Journal Article |
| Year of Publication | 2002 |
| Authors | Hayton, TW, Legzdins, P, Rettig, SJ |
| Journal | Acta Crystallographica Section C-Crystal Structure Communications |
| Volume | 58 |
| Pagination | m68-m69 |
| Date Published | Feb |
| Type of Article | Article |
| ISBN Number | 0108-2701 |
| Keywords | BONDS, COMPLEXES, FRAGMENT, REACTIVITY |
| Abstract | The title complex, [Mo(C5H5)(C6H4FO)(C4H11Si)(NO)], is formed by reacting CpMo(NO)(CH2SiMe3)(2), where Cp is cyclopentadienyl, with one equivalent of p-FC6H4OH. The complex exhibits the expected piano-stool molecular structure, with a linear nitrosyl ligand [Mo-N-O 168.2 (2)degrees] having Mo-N and N-O distances of 1.764 (2) and 1.207 (3) Angstrom, respectively. The phenoxo Mo-O distance of 1.945 (2) Angstrom is suggestive of some multiple-bond character. |
| URL | <Go to ISI>://000173796300004 |
