Title | Electronic interaction anisotropy between open-shell lanthanide atoms and helium from cold collision experiment |
Publication Type | Journal Article |
Year of Publication | 2005 |
Authors | Krems, RV, Buchachenko, AA |
Journal | JOURNAL OF CHEMICAL PHYSICS |
Volume | 123 |
Pagination | 101101 |
Date Published | SEP 8 |
ISSN | 0021-9606 |
Abstract | Based on measurements of the Zeeman relaxation in a cold gas of He-3 {[}C. I. Hancox, S. C. Doret, M. I. Hummon, L. Luo, and J. M. Doyle, Nature (London) 431, 281 (2004)], we show that the electronic interaction anisotropy between rare-earth atoms with nonzero electronic orbital angular momenta and helium is extremely small. The interaction of the rare-earth atoms with He gives rise to several adiabatic potentials with different electronic symmetries. It is demonstrated that the energy splitting between these potentials does not exceed 0.09 cm(-1) at interatomic distances larger than the turning point for collisions at 0.8 K, including the region of the van der Waals interaction minima. (c) 2005 American Institute of Physics. |
DOI | 10.1063/1.2052687 |
