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  3. DOUBLE METALATION AND IRON OSMIUM BONDING INVOLVING FERROCENYL MOIETIES ON CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PPRI2)] AND H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PFCET)]

DOUBLE METALATION AND IRON OSMIUM BONDING INVOLVING FERROCENYL MOIETIES ON CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PPRI2)] AND H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PFCET)]

TitleDOUBLE METALATION AND IRON OSMIUM BONDING INVOLVING FERROCENYL MOIETIES ON CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURES OF H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PPRI2)] AND H2OS3(CO)8[(ETA-C5H4)FE(ETA-C5H3PFCET)]
Publication TypeJournal Article
Year of Publication1992
AuthorsCullen, WR, Rettig, SJ, Zheng, TC
JournalOrganometallics
Volume11
Pagination3434-3439
Date PublishedOct
Type of ArticleArticle
ISBN Number0276-7333
KeywordsATOMS, COMPLEXES, FE, PD(BF4)2
Abstract

{Thermolysis of Os3(CO)11(PFcPR2i) and Os3(CO)11(PEtFc2) (FcH = Fe(eta-C5H5)2) affords the title compounds, {mu3-[(eta-C5H4)Fe(eta-C5H3PPr2i)]}(mu-H)2Os3(CO)8 (7) and {mu3-[(eta-C5H4)Fe(eta5H3PEtFc)]}(mu-H)2Os3(CO)8 (8), in 15 and 25% yield, respectively. The structures of 7 and 8 are very similar and they both contain a doubly metalated ferrocenyl moiety, the iron atom of which is bonded to one osmium atom m the cluster. 7: triclinic
URL<Go to ISI>://A1992JT75400050