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Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS-H across a phosphine-bridged Pd-I-Pd-I bond

TitleDiastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS-H across a phosphine-bridged Pd-I-Pd-I bond
Publication TypeJournal Article
Year of Publication2003
AuthorsFoo, SJL, Jones, ND, Patrick, BO, James, BR
JournalChemical Communications
Pagination988-989
Type of ArticleArticle
ISBN Number1359-7345
KeywordsBEHAVIOR, H2S, palladium, REACTIVITY
Abstract

{The ligand CH2(P(o-C6H4NMe2)(2))(2) (dmapm) gives access to the first example of a dipalladium(I) complex supported by a tetradentate ligand, Pd2Cl2(mu-N,P,P,N-dmapm), which, unlike the well-known Pd2X2(mu-dppm)(2) complexes (X = halide

URL<Go to ISI>://000182008200029