|Title||Determination of shapes and maximums of analyte peaks based on solute mobilitiess in capillary electrophoresis|
|Publication Type||Journal Article|
|Year of Publication||2004|
|Authors||Fang, N, Ting, E, Chen, DDY|
|Type of Article||Article|
|Keywords||DISPERSION, DYNAMIC COMPLEXATION, FLOW, MIGRATION BEHAVIOR, NUMERICAL-SIMULATION, pressure, QUANTITATIVE DESCRIPTION, SEPARATIONS, ZONE-ELECTROPHORESIS|
In capillary electrophoresis, the relative orders of mobilities of analyte, additive, and the complex formed determine the analyte peak shape in a way similar to the way the binding isotherms determine the peak shapes in chromatography. The three mobilities allow six possible orders; each produces a characteristic peak shape in CE. Equations describing the analyte migration in a CE system with the presence of mobility-changing additives can be implemented into computer programs to predict the migration times of the analyte peak maximums, and the predicted migration times agree well with the experimental results.
|URL||<Go to ISI>://000220225200023|