| Title | Cyclometalated Ru Complexes of Type [Ru-II((NN)-N-boolean AND)(2)((CN)-N-boolean AND)](z): Physicochemical Response to Substituents Installed on the Anionic Ligand |
| Publication Type | Journal Article |
| Year of Publication | 2010 |
| Authors | Bomben, PG, Koivisto, BD, Berlinguette, CP |
| Journal | INORGANIC CHEMISTRY |
| Volume | 49 |
| Pagination | 4960-4971 |
| Date Published | JUN 7 |
| ISSN | 0020-1669 |
| Abstract | {The electrochemical and photophysical properties of a series of Ru(II) complexes related to {[}Ru(dcbpyH(2))(2)(ppy)(1+) (1; dcbpyH(2) = 4,4'-dicarboxy-2,2'-bipyridine; ppy = 2-phenylpyridine) were examined to elucidate the effect of modifying the anionic fragment of the (CN)-N-boolean AND ligand with conjugated substituents (R). Included in this study is a family of compounds (2-5) consisting of one or two -NO2 groups installed meta, ortho, and para to the organometallic bond. A suite of compounds with electron-donating and withdrawing groups (e.g. |
| DOI | 10.1021/ic100063c |
