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CRYSTAL TO MOLECULAR CHIRALITY TRANSFER - SUPRAMOLECULAR PHOTOCHEMISTRY OF CRYSTALLINE CARBOXYLATE SALTS

TitleCRYSTAL TO MOLECULAR CHIRALITY TRANSFER - SUPRAMOLECULAR PHOTOCHEMISTRY OF CRYSTALLINE CARBOXYLATE SALTS
Publication TypeJournal Article
Year of Publication1992
AuthorsJones, R, Scheffer, JR, Trotter, J, Yang, J
JournalTetrahedron Letters
Volume33
Pagination5481-5484
Date PublishedSep
Type of ArticleArticle
ISBN Number0040-4039
KeywordsASYMMETRIC INDUCTION, REACTIVITY, SOLID-STATE PHOTOCHEMISTRY
Abstract

Solid state irradiation of a salt formed between a prochiral, photochemically reactive carboxylic acid and a non-absorbing, optically active amine is shown to lead to an optically active Norrish type II photoproduct whose optical purity depends on the dimorphic crystalline modification photolyzed.

URL<Go to ISI>://A1992JN76700003