Research & Teaching Faculty

  1. Research & Teaching Faculty
  2. Department Publications
  3. CRYSTAL AND MOLECULAR-STRUCTURES OF 2 TRIOSMIUM CARBONYL CLUSTER COMPLEXES CONTAINING ORTHO-METALATED PHENYLPHOSPHINES (MU-H)OS3(CO)8L[PFCPH(C6H4)] (L = PFCPH2 OR CO)

CRYSTAL AND MOLECULAR-STRUCTURES OF 2 TRIOSMIUM CARBONYL CLUSTER COMPLEXES CONTAINING ORTHO-METALATED PHENYLPHOSPHINES (MU-H)OS3(CO)8L[PFCPH(C6H4)] (L = PFCPH2 OR CO)

TitleCRYSTAL AND MOLECULAR-STRUCTURES OF 2 TRIOSMIUM CARBONYL CLUSTER COMPLEXES CONTAINING ORTHO-METALATED PHENYLPHOSPHINES (MU-H)OS3(CO)8L[PFCPH(C6H4)] (L = PFCPH2 OR CO)
Publication TypeJournal Article
Year of Publication1992
AuthorsCullen, WR, Rettig, SJ, Zheng, TC
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume70
Pagination2215-2223
Date PublishedAug
Type of ArticleArticle
ISBN Number0008-4042
KeywordsBENZYNE, OSMIUM
Abstract

{Pyrolysis of Os3(CO)11(PFcPh2), 7, and Os3(CO)10(PFcPh2)2, 8, (FcH = (Fe(eta-C5H5)2 affords (mu-H)Os3(CO)9[PFcPh(C6H4)], 5, and (mu-H)Os3(CO)8(FcPPh2)[PFcPh(C6H4)], 6, respectively. The structures of 5 and 6 are analogous; they both contain a bridging hydride and a mu3-PFcPh(C6H4) moiety resulting from the ortho-metalation of one phenyl group and subsequent formation of a eta2-bond from that metalated phenyl to the third osmium atom. Crystals of 5, are triclinic
URL<Go to ISI>://A1992JW56400011