| Title | COORDINATION CHEMISTRY OF 2-(2’-HYDROXYPHENYL)-2-OXAZOLINES WITH ALUMINUM, GALLIUM, AND INDIUM - 1ST TRIS(LIGAND)METAL(III) COMPLEXES OF THIS NATURALLY-OCCURRING BINDING GROUP |
| Publication Type | Journal Article |
| Year of Publication | 1992 |
| Authors | Hoveyda, HR, Karunaratne, V, Rettig, SJ, Orvig, C |
| Journal | Inorganic Chemistry |
| Volume | 31 |
| Pagination | 5408-5416 |
| Date Published | Dec |
| Type of Article | Article |
| ISBN Number | 0020-1669 |
| Keywords | CHIRAL, CRYSTAL-STRUCTURE, ENTEROBACTIN, INTRAMOLECULAR REARRANGEMENT REACTIONS, ISOMERIZATION, KINETICS, LIGANDS, MICROBIAL IRON TRANSPORT, PROBABLE MECHANISM, SIDEROPHORES, TRIS-CHELATE COMPLEXES |
| Abstract | {A series of tris(ligand)metal(III) complexes of group 13 metals (Al, Ga, In) with 2-(2’-hydroxyphenyl)-2-oxazoline (Hoz), 2-(5’-bromo-2’-hydroxyphenyl)-2-oxazoline (HBroz), 2-(2’-hydroxy-3’-methylphenyl)-2-oxazoline(Hmoz), 2-(2’-hydroxy-3’-allylphenyl)-2-oxazoline (Haloz) have been prepared. These compounds have been studied by a variety of techniques including variable-temperature NMR (H-1 and Al-27) and single-crystal X-ray diffraction. The M(OZ)3-CH3OH complexes (M = Al, Ga, In) are isomorphous and isostructural. Crystallographic data for C28H28MN3O7: monoclinic |
| URL | <Go to ISI>://A1992KE75400016 |
