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The complexes: RhCl(P-N)(THP), where P-N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P-N][THP(O)] containing O-bonded phosphine oxides

TitleThe complexes: RhCl(P-N)(THP), where P-N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P-N][THP(O)] containing O-bonded phosphine oxides
Publication TypeJournal Article
Year of Publication2008
AuthorsLorenzini, F, Patrick, BO, James, BR
JournalInorganica Chimica Acta
Volume361
Pagination3199-3204
Date PublishedJul
Type of ArticleArticle
ISBN Number0020-1693
KeywordsBEARING O-N, BIDENTATE PHOSPHINES, CATALYTIC-OXIDATION, HYDROFORMYLATION, LIGANDS, LOW-TEMPERATURE, N-DIMETHYLANILINYL SUBSTITUENTS, OXIDATION, PALLADIUM(II) COMPLEXES, phosphanes, phosphine oxides, phosphines, REACTIVITY, RHODIUM COMPLEXES, RHODIUM(I) COMPLEXES, X-ray structure
Abstract

{The complex RhCl(P-N)(THP) (1) is synthesized under argon from RhCl(cod)(THP) and P-N, and is structurally characterized; P-N = P, N-chelated o-diphenylphosphino-N,N-dimethylaniline

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