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  3. The co-crystallization of Ru((R)-binap)(eta(3)-Me-allyl)(2) and binap dioxide, and synthesis of Ru(Ph2P(CH2)(4)PPh2)(eta(3)-Me-allyl)(2)

The co-crystallization of Ru((R)-binap)(eta(3)-Me-allyl)(2) and binap dioxide, and synthesis of Ru(Ph2P(CH2)(4)PPh2)(eta(3)-Me-allyl)(2)

TitleThe co-crystallization of Ru((R)-binap)(eta(3)-Me-allyl)(2) and binap dioxide, and synthesis of Ru(Ph2P(CH2)(4)PPh2)(eta(3)-Me-allyl)(2)
Publication TypeJournal Article
Year of Publication1998
AuthorsMacfarlane, KS, Rettig, SJ, Liu, ZQ, James, BR
JournalJournal of Organometallic Chemistry
Volume557
Pagination213-219
Date PublishedApr
Type of ArticleArticle
ISBN Number0022-328X
Keywordsallyl, ASYMMETRIC HYDROGENATION, BINAP, CATALYSTS, COMPLEXES, ENANTIOSELECTIVE HYDROGENATION, GENERAL-SYNTHESIS, KINETICS, rhodium, ruthenium, RUTHENIUM(II) COMPLEXES, X-ray crystal structure
Abstract

{The molecular structure of the 2-methylallyl species Ru((R)-binap)(eta(3)-Me-allyl)(2) (3) was established by X-ray crystallography of a crystal of 3a, the asymmetric unit of which is composed of half of a molecule of 3 and half of a (R)-(+)-2,2’-bis(-diphenylphosphinoyl)-1,1’-binaphthyl(binap dioxide) molecule, co-crystallized with two disordered deuterobenzenes; crystals of 3a are tetragonal, space group I422, with Z = 8
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