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Characterization of five-coordinate ruthenium(II) phosphine complexes by X-ray diffraction and solid-state P-31 CP/MAS NMR studies and their reactivity with sulfoxides and thioethers

TitleCharacterization of five-coordinate ruthenium(II) phosphine complexes by X-ray diffraction and solid-state P-31 CP/MAS NMR studies and their reactivity with sulfoxides and thioethers
Publication TypeJournal Article
Year of Publication1996
AuthorsMacfarlane, KS, Joshi, AM, Rettig, SJ, James, BR
JournalInorganic Chemistry
Volume35
Pagination7304-7310
Date PublishedDec
Type of ArticleArticle
ISBN Number0020-1669
Keywordsamine, ANGLE SPINNING TECHNIQUES, CATALYSTS, DERIVATIVES, IMINE, LIGANDS, NUCLEAR MAGNETIC-RESONANCE, PLATINUM(II), triphenylphosphine
Abstract

{P-31 CP/MAS NMR spectroscopy is examined as a method of characterization for ruthenium(II) phosphine complexes in the solid state, and the results are compared with X-ray crystallographic data determined for RuCl2(dppb)(PPh(3)) (dppb = Ph(2)P(CH2)(4)PPh(2)), RuBr2(PPh(3))(3), and the previously determined RuCl2(PPh(3))(3). Crystals of RuBr2(PPh(3))(3) (C54H45Br2P3Ru) are monoclinic, space group P2(1)/a, with a = 12.482(4) Angstrom

URL<Go to ISI>://A1996VW81900019