Title | Cationic iron(III) complex with a hexadentate N-2,N ’(2),O-2-aminopyridylphenolate ligand |
Publication Type | Journal Article |
Year of Publication | 1999 |
Authors | Setyawati, IA, Rettig, SJ, Orvig, C |
Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
Volume | 77 |
Pagination | 2033-2038 |
Date Published | Dec |
Type of Article | Article |
ISBN Number | 0008-4042 |
Keywords | ANALOGS, BINDING-SITE, CATIONIC, CRYSTAL-STRUCTURE, gallium, hexadentate, indium, iron( III), LACTOFERRIN, MODEL, OXO, phenolate, PROTEINS, pyridyl |
Abstract | {Iron(III) complexation with potentially hexadentate H(2)bbpen (N,N’-bis(2-hydroxybenzyl)-N,N’-bis(2-methylpyridyl)ethylenediamine) was studied. The resulting monocationic complex, [Fe(bbpen)](+) as its NO3- and PF6- salts, was characterized by infrared spectroscopy, mass spectrometry, elemental analyses, cyclic voltammetry, and X-ray crystallographic analysis. Crystals of [Fe(bbpen)]NO3. CH3OH are monoclinic, space group P2(1)/c |
URL | <Go to ISI>://000084067500004 |
